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Dess-Martin periodinane

Product Code. 15429029
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Quantity:
50 g
Unit Size:
50g
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Product Code. 15429029

Brand: Thermo Scientific Alfa Aesar L15779.18

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Description

CAS: 87413-09-0 | C13H13IO8 | 424.14 g/mol

Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.

Solubility
Soluble in chloroform, acetone, acetonitrile and methylene chloride. Slightly soluble in ether and hexane.

Notes
Store in cool place. Air and moisture sensitive. Incompatible with strong reducing agents, combustible material and water.
TRUSTED_SUSTAINABILITY

Specifications

CAS 87413-09-0
Melting Point 130°C to 132°C (decomposition)
Molecular Formula C13H13IO8
MDL Number MFCD00130127
Quantity 50 g
UN Number UN1479
Beilstein 4548207
Sensitivity Air, light, and moisture sensitive
Merck Index 14,2933
Synonym dess-martin periodinane, triacetoxyperiodinane, 1,1,1-triacetoxy-1,1-dihydro-1,2-benziodoxol-3 1 h-one, dess-martin reagent, dess-martinperiodinane
Solubility Information Soluble in chloroform,acetone,acetonitrile and methylene chloride. Slightly soluble in ether and hexane.
InChI Key NKLCNNUWBJBICK-UHFFFAOYSA-N
SMILES CC(=O)O[I]1(OC(C)=O)(OC(C)=O)OC(=O)C2=CC=CC=C12
IUPAC Name (1,1-diacetyloxy-3-oxo-1$l^{5},2-benziodoxol-1-yl) acetate
Molecular Weight (g/mol) 424.14
PubChem CID 159087
Formula Weight 424.15
Percent Purity ≥95%
Chemical Name or Material Dess-Martin periodinane
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