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Lithium diisopropylamide, 2M sol. in THF/n-heptane/ethylbenzene, AcroSeal™

CAS: 4111-54-0 Molecular Formula: C6H14LiN Molecular Weight (g/mol): 107.125 MDL Number: MFCD00064449 InChI Key: ZCSHNCUQKCANBX-UHFFFAOYSA-N Synonym: lithium diisopropylamide,unii-ol028kiw1i,lithium di-isopropylamide,lithium diisopropyl amide,2-propanamine, n-1-methylethyl-, lithium salt,ol028kiw1i,lithium di propan-2-yl azanide,2-propanamine, n-1-methylethyl-, lithium salt 1:1,lithium n,n-diisopropylamide,ipr2nli PubChem CID: 2724682 IUPAC Name: lithium;di(propan-2-yl)azanide SMILES: [Li+].CC(C)[N-]C(C)C

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General Chemistry Solutions

PubChem CID	2724682
CAS	4111-54-0
Molecular Weight (g/mol)	107.125
MDL Number	MFCD00064449
SMILES	[Li+].CC(C)[N-]C(C)C
Synonym	lithium diisopropylamide,unii-ol028kiw1i,lithium di-isopropylamide,lithium diisopropyl amide,2-propanamine, n-1-methylethyl-, lithium salt,ol028kiw1i,lithium di propan-2-yl azanide,2-propanamine, n-1-methylethyl-, lithium salt 1:1,lithium n,n-diisopropylamide,ipr2nli
IUPAC Name	lithium;di(propan-2-yl)azanide
InChI Key	ZCSHNCUQKCANBX-UHFFFAOYSA-N
Molecular Formula	C6H14LiN

Methyllithium, 1.6M sol. in diethyl ether (± 5% w/v), AcroSeal™, Thermo Scientific Chemicals

CAS: 917-54-4 Molecular Formula: CH3Li Molecular Weight (g/mol): 21.98 MDL Number: MFCD00008253 InChI Key: DVSDBMFJEQPWNO-UHFFFAOYSA-N Synonym: methyllithium,lithium, methyl,methyl lithium,lithium methanide,meli,lithium methyl,lithium carbanide,lithium methide,methllithium,methyllithum PubChem CID: 2724049 SMILES: [Li]C

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General Chemistry Solutions

PubChem CID	2724049
CAS	917-54-4
Molecular Weight (g/mol)	21.98
MDL Number	MFCD00008253
SMILES	[Li]C
Synonym	methyllithium,lithium, methyl,methyl lithium,lithium methanide,meli,lithium methyl,lithium carbanide,lithium methide,methllithium,methyllithum
InChI Key	DVSDBMFJEQPWNO-UHFFFAOYSA-N
Molecular Formula	CH3Li

Tetrabutylammonium fluoride, 1M solution in THF, AcroSeal™

CAS: 429-41-4 | C16H36FN | 261.47 g/mol

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Ammonium Salts

Linear Formula	[CH₃(CH₂)₃]₄NF
Molecular Weight (g/mol)	261.47
ChEBI	CHEBI:51990
Color	Brown to Green
Physical Form	Solution
SMILES	[F-].CCCC[N+](CCCC)(CCCC)CCCC
Merck Index	15,9332
InChI Key	FPGGTKZVZWFYPV-UHFFFAOYSA-M
Density	0.8870g/mL
PubChem CID	2724141
Concentration or Composition (by Analyte or Components)	0.90 to 1.10M
CAS	7732-18-5
Health Hazard 3	GHS P Statement Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Wear protective gloves/protective clothing/eye p
MDL Number	MFCD00011747
Health Hazard 2	GHS H Statement Causes severe skin burns and eye damage. Suspected of causing cancer. May cause respiratory irritation. Highly flammable liquid and vapor. May form explosive peroxides. May cause drowsiness or dizzines
Flash Point	−17°C
Health Hazard 1	GHS Signal Word: Danger
Synonym	tetrabutylammonium fluoride,tbaf,tetrabutylazanium fluoride,tetrabutyl ammonium fluoride,tetra-n-butylammonium fluoride,tetrabutylamine, fluoride,n,n,n-tributylbutan-1-aminium fluoride,1-butanaminium, n,n,n-tributyl-, fluoride,n,n,n-tributyl-1-butanaminium fluoride,1-butanaminium, n,n,n-tributyl-, fluoride 1:1
IUPAC Name	tetrabutylazanium;fluoride
Molecular Formula	C16H36FN
EINECS Number	207-057-2
Formula Weight	261.46
Specific Gravity	0.887

Diisobutylaluminium hydride, 1M solution in hexane, AcroSeal™

CAS: 1191-15-7 | C₈H₁₉Al | 142.22 g/mol

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Organoaluminum

Linear Formula	[(CH₃)₂CHCH₂]₂AlH
Molecular Weight (g/mol)	142.22
Physical Form	Solution
Chemical Name or Material	Diisobutylaluminium hydride
Merck Index	15, 3212
Density	0.7010g/mL
Name Note	1M Solution in Hexane
Fieser	01,260; 02,140; 03,101; 04,158; 05,224; 06,198; 07,111; 08,173; 09,171; 10,149; 11,185; 12,191; 13,115; 14,138; 15,137; 16,27; 17,123
CAS	110-54-3
Health Hazard 3	GHS P Statement IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,if present and easy to do. Continue rinsing. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective g
MDL Number	MFCD00008928
Health Hazard 2	GHS H Statement May be fatal if swallowed and enters airways. Toxic to aquatic life with long lasting effects. Causes severe skin burns and eye damage. May cause drowsiness or dizziness. May cause damage to organs through p
Solubility Information	Solubility in water: reacts
Flash Point	−23°C
Health Hazard 1	GHS Signal Word: Danger
Synonym	DIBAL-H
Beilstein	04, IV, 4400
Molecular Formula	C₈H₁₉Al
EINECS Number	214-729-9
Formula Weight	142.22
Specific Gravity	0.701
Melting Point	-70.0°C

Vinylmagnesium bromide, 0.7M solution in THF, AcroSeal™

CAS: 1826-67-1 Molecular Formula: C2H3BrMg Molecular Weight (g/mol): 131.26 MDL Number: MFCD00000042 InChI Key: XHHHAXOHMKAOSL-UHFFFAOYSA-M Synonym: vinylmagnesium bromide,bromo ethenyl magnesium,vinyl magnesium bromide,magnesium, bromoethenyl,vinylmagnesium bromide solution,vinylmagnesium bromide solution, 1.0 m in thf,bromovinylmagnesium,bromo vinyl magnesium,vinyl magnesiumbromide,grignard reagent PubChem CID: 74584 SMILES: Br[Mg]C=C

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General Chemistry Solutions

PubChem CID	74584
CAS	1826-67-1
Molecular Weight (g/mol)	131.26
MDL Number	MFCD00000042
SMILES	Br[Mg]C=C
Synonym	vinylmagnesium bromide,bromo ethenyl magnesium,vinyl magnesium bromide,magnesium, bromoethenyl,vinylmagnesium bromide solution,vinylmagnesium bromide solution, 1.0 m in thf,bromovinylmagnesium,bromo vinyl magnesium,vinyl magnesiumbromide,grignard reagent
InChI Key	XHHHAXOHMKAOSL-UHFFFAOYSA-M
Molecular Formula	C2H3BrMg

Boron trifluoride etherate, ca. 48% BF3, AcroSeal™

CAS: 109-63-7 Molecular Formula: C4H10BF3O Molecular Weight (g/mol): 141.93 MDL Number: MFCD00013194 InChI Key: KZMGYPLQYOPHEL-UHFFFAOYSA-N Synonym: Boron trifluoride ethyl ether PubChem CID: 8000 IUPAC Name: ethoxyethane;trifluoroborane SMILES: FB(F)F.CCOCC

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Enediols

PubChem CID	8000
CAS	109-63-7
Molecular Weight (g/mol)	141.93
MDL Number	MFCD00013194
SMILES	FB(F)F.CCOCC
Synonym	Boron trifluoride ethyl ether
IUPAC Name	ethoxyethane;trifluoroborane
InChI Key	KZMGYPLQYOPHEL-UHFFFAOYSA-N
Molecular Formula	C4H10BF3O

Borane dimethyl sulfide complex, 2M solution in THF, AcroSeal™

CAS: 13292-87-0 | C2H9BS | 75.96 g/mol

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General Chemistry Solutions

Linear Formula	(CH₃)₂S·BH₃
Molecular Weight (g/mol)	75.96
InChI Key	RMHDLBZYPISZOI-UHFFFAOYSA-N
Density	0.8500g/mL
PubChem CID	9833925
Name Note	2M Solution in Tetrahydrofuran
Fieser	04,191; 05,47; 06,64; 08,49; 10,49; 14,52; 17,50
RTECS Number	PV5080000
Formula Weight	75.95
Color	Colorless to Yellow
Physical Form	Solution
Chemical Name or Material	Borane-methyl sulfide complex
SMILES	B.CSC
Merck Index	15, 1336
Concentration	1.80 to 2.20M
CAS	75-18-3
Health Hazard 3	GHS P Statement Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Handle under inert gas. Protect from moisture. Wear protective gloves/protective clothing/eye protection/face protection. If skin irritation occurs: Get medical advice/attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.
MDL Number	MFCD00013189
Health Hazard 2	GHS H Statement May cause respiratory irritation. Causes skin irritation. Causes serious eye damage. Harmful if swallowed. In contact with water releases flammable gases which may ignite spontaneously. Highly flammable liquid and vapor. May form explosive peroxides. Reacts violently with water. Suspected of causing cancer. May cause drowsiness or dizziness.
Flash Point	−17°C
Solubility Information	Solubility in water: reacts. Other solubilities: soluble in ethyl ether, tetrahydrofurane, hexane,, toluene, methylene chloride and other aprotic, solvents
Health Hazard 1	Danger
Synonym	dimethyl sulfide borane,borane-methyl sulfide complex,borane dimethyl sulfide complex,borane-dimethyl sulfide,dimethyl sulfideborane,dimethyl sulfide trihydroboron,borane-dimethyl sulfide complex,borane methylsulfide,borane dimethylsulfide,borane dms
TSCA	TSCA
IUPAC Name	(methylsulfanyl)methane borane
Molecular Formula	C2H9BS
EINECS Number	236-313-6
Specific Gravity	0.85

Thiophenol, 99%, AcroSeal™

CAS: 108-98-5 Molecular Formula: C₆H₆S Molecular Weight (g/mol): 110.17 MDL Number: MFCD00004826 InChI Key: RMVRSNDYEFQCLF-UHFFFAOYSA-N Synonym: thiophenol,phenyl mercaptan,mercaptobenzene,phenylthiol,phenylmercaptan,thiofenol,phenol, thio,thiophenate,thiofenol czech,benzene, mercapto PubChem CID: 7969 ChEBI: CHEBI:48498 IUPAC Name: benzenethiol SMILES: C1=CC=C(C=C1)S

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Thiophenols

PubChem CID	7969
CAS	108-98-5
Molecular Weight (g/mol)	110.17
ChEBI	CHEBI:48498
MDL Number	MFCD00004826
SMILES	C1=CC=C(C=C1)S
Synonym	thiophenol,phenyl mercaptan,mercaptobenzene,phenylthiol,phenylmercaptan,thiofenol,phenol, thio,thiophenate,thiofenol czech,benzene, mercapto
IUPAC Name	benzenethiol
InChI Key	RMVRSNDYEFQCLF-UHFFFAOYSA-N
Molecular Formula	C₆H₆S

Lithium borohydride, 4M (10 wt.%) solution in THF, AcroSeal™

CAS: 16949-15-8 | BH4Li | 21.78 g/mol

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Alkali Metal Salts

Linear Formula	LiBH₄
Molecular Weight (g/mol)	21.78
SMILES	[Li+].[BH4-]
Merck Index	15,5581
InChI Key	UUKMSDRCXNLYOO-UHFFFAOYSA-N
Density	0.8900g/mL
PubChem CID	20722760
CAS	109-99-9
Health Hazard 3	GHS P Statement Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Handle under inert gas. Protect from moisture
MDL Number	MFCD00011088
Health Hazard 2	GHS H Statement Highly flammable liquid and vapor. In contact with water releases flammable gases which may ignite spontaneously. Harmful if swallowed. Causes severe skin burns and eye damage. May cause respiratory irritati
Solubility Information	Solubility in water: decomposes
Flash Point	−21°C
Health Hazard 1	GHS Signal Word: Danger
Synonym	borate 1-, tetrahydro-, lithium,unii-8l87x4s4kp,boryllithium,lithium, boryl,lithium hydroborate,lithotab borohydride,bh4li,lithium 1+ ion boranuide,lithium borohydride 2.0 m in thf,borate 1-, tetrahydro-, lithium 1:1
IUPAC Name	lithium;boron(1-)
Molecular Formula	BH4Li
EINECS Number	241-021-7
Formula Weight	21.77
Specific Gravity	0.89

Lithium aluminum hydride, 1M solution in THF, AcroSeal™

CAS: 16853-85-3 | AlH4Li | 37.95 g/mol

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General Chemistry Solutions

Linear Formula	LiAlH₄
Molecular Weight (g/mol)	37.95
Color	Gray
Physical Form	Turbid Solution
Chemical Name or Material	Lithium Aluminum hydride
SMILES	[Li+].[AlH4-]
Merck Index	15, 344
InChI Key	OCZDCIYGECBNKL-UHFFFAOYSA-N
Density	0.9000g/mL
PubChem CID	21226445
Percent Purity	3.9 to 4.5% (as LiAlH4)
Fieser	01,581; 02,242; 03,176; 04,291; 05,382; 06,325; 07,196; 08,286; 09,274; 10,236; 11,289; 12,272; 13,61; 14,190; 15,184; 16,133; 17,162
CAS	109-99-9
Health Hazard 3	GHS P Statement Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Handle under inert gas. Protect from moisture. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.
MDL Number	MFCD00011075
Health Hazard 2	GHS H Statement May cause respiratory irritation. Causes skin irritation. Causes serious eye damage. Highly flammable liquid and vapor. In contact with water releases flammable gases which may ignite spontaneously. May form explosive peroxides. Suspected of causing cancer. Harmful if swallowed. May cause drowsiness or dizziness.
Flash Point	−17°C
Solubility Information	Solubility in water: vigorous reaction.
Health Hazard 1	Danger
Synonym	lithium aluminum hydride,lithium aluminum hydride,aluminum lithium hydride,lithiumaluminiumhydride,aluminum iii lithium hydride,lithium alanate,lithium aluminum tetrahydride,lithiumaluminiumhydrid,litiumaluminum hydride,lithim aluminum hydride
IUPAC Name	lithium(1+) alumanuide
Molecular Formula	AlH4Li
Formula Weight	37.95
Specific Gravity	0.9

Ethynylmagnesium bromide, 0.5M solution in THF, AcroSeal™

CAS: 4301-14-8 Molecular Formula: C2HBrMg Molecular Weight (g/mol): 129.24 MDL Number: MFCD00075342 InChI Key: HUGJUYPSXULVQQ-UHFFFAOYSA-M Synonym: ethynylmagnesium bromide,bromo ethynyl magnesium,ethynylmagnesium bromide solution,ethinylmagnesium bromide,ethynyl magnesiumbromide,pubchem18180,ethynyl-magnesium bromide,ethinyl magnesium bromide,ethynyl magnesium bromide,hugjuypsxulvqq-uhfffaoysa-m,grignard reagent PubChem CID: 4071243 IUPAC Name: bromo(ethynyl)magnesium SMILES: Br[Mg]C#C

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Alkaline Earth Metal Salts

PubChem CID	4071243
CAS	4301-14-8
Molecular Weight (g/mol)	129.24
MDL Number	MFCD00075342
SMILES	Br[Mg]C#C
Synonym	ethynylmagnesium bromide,bromo ethynyl magnesium,ethynylmagnesium bromide solution,ethinylmagnesium bromide,ethynyl magnesiumbromide,pubchem18180,ethynyl-magnesium bromide,ethinyl magnesium bromide,ethynyl magnesium bromide,hugjuypsxulvqq-uhfffaoysa-m,grignard reagent
IUPAC Name	bromo(ethynyl)magnesium
InChI Key	HUGJUYPSXULVQQ-UHFFFAOYSA-M
Molecular Formula	C2HBrMg

N,N,N',N'-Tetramethylethylenediamine, 99.5%, purified by redistillation, AcroSeal™

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Tertiary amines

Diisopropylamine, 99.5%, redistilled, AcroSeal™, Thermo Scientific Chemicals

CAS: 108-18-9 Molecular Formula: C₆H₁₅N Molecular Weight (g/mol): 101.19 MDL Number: MFCD00008862 InChI Key: UAOMVDZJSHZZME-UHFFFAOYSA-N Synonym: diisopropylamine,2-propanamine, n-1-methylethyl,n-1-methylethyl-2-propanamine,dipa,n,n-diisopropylamine,bis propan-2-yl amine,n-isopropylpropan-2-amine,di-isopropylamine,n-isopropyl-1-amino-2-methylethane,diisopropyl amine PubChem CID: 7912 IUPAC Name: N-propan-2-ylpropan-2-amine SMILES: CC(C)NC(C)C

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Secondary amines

PubChem CID	7912
CAS	108-18-9
Molecular Weight (g/mol)	101.19
MDL Number	MFCD00008862
SMILES	CC(C)NC(C)C
Synonym	diisopropylamine,2-propanamine, n-1-methylethyl,n-1-methylethyl-2-propanamine,dipa,n,n-diisopropylamine,bis propan-2-yl amine,n-isopropylpropan-2-amine,di-isopropylamine,n-isopropyl-1-amino-2-methylethane,diisopropyl amine
IUPAC Name	N-propan-2-ylpropan-2-amine
InChI Key	UAOMVDZJSHZZME-UHFFFAOYSA-N
Molecular Formula	C₆H₁₅N

Isopropylmagnesium chloride, 2.0M solution in THF, AcroSeal™

CAS: 1068-55-9 Molecular Formula: C3H7ClMg Molecular Weight (g/mol): 102.84 MDL Number: MFCD00000466 InChI Key: GPIBKUJXKCEZOH-UHFFFAOYSA-M Synonym: isopropylmagnesium chloride,magnesium, chloro 1-methylethyl,chloro 1-methylethyl magnesium,i-prmgcl,isopropylmagnesiumchloride,chloro isopropyl magnesium,isopropyl magnesium chloride,isopropylmagnesium chloride solution,iprmgcl,ipr-mgcl PubChem CID: 101955 SMILES: CC(C)[Mg]Cl

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General Chemistry Solutions

PubChem CID	101955
CAS	1068-55-9
Molecular Weight (g/mol)	102.84
MDL Number	MFCD00000466
SMILES	CC(C)[Mg]Cl
Synonym	isopropylmagnesium chloride,magnesium, chloro 1-methylethyl,chloro 1-methylethyl magnesium,i-prmgcl,isopropylmagnesiumchloride,chloro isopropyl magnesium,isopropyl magnesium chloride,isopropylmagnesium chloride solution,iprmgcl,ipr-mgcl
InChI Key	GPIBKUJXKCEZOH-UHFFFAOYSA-M
Molecular Formula	C3H7ClMg

Potassium tert-butoxide, pure, 1.6-1.7M (20 wt.%) solution in THF, AcroSeal™

CAS: 865-47-4 | C₄H₉KO | 112.21 g/mol

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Alkali Metal Salts

Linear Formula	(CH₃)₃COK
Molecular Weight (g/mol)	112.21
InChI Key	LPNYRYFBWFDTMA-UHFFFAOYSA-N
Density	0.9290g/mL
PubChem CID	23665647
Name Note	Pure, 1.7M (20 wt.%) solution in THF
Formula Weight	112.21
Color	Amber to Yellow
Physical Form	Solution
Chemical Name or Material	Potassium tert-butoxide
Grade	Pure
SMILES	CC(C)(C)[O-].[K+]
Concentration or Composition (by Analyte or Components)	1.60 to 1.75M
CAS	109-99-9
Health Hazard 3	GHS P Statement Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Wear protective gloves/protective clothing/eye p
MDL Number	MFCD00012162
Health Hazard 2	GHS H Statement Causes severe skin burns and eye damage. May cause respiratory irritation. Highly flammable liquid and vapour. Suspected of causing cancer. Reacts violently with water. May form explosive peroxides.<br
Packaging	AcroSeal™ Glass Bottle
Solubility Information	Solubility in water: reacts with water
Flash Point	−21°C
Health Hazard 1	GHS Signal Word: Danger
Synonym	potassium tert-butoxide,potassium tert-butanolate,potassium t-butoxide,potassium 2-methylpropan-2-olate,potassium tert-butylate,kotbu,2-methyl-2-propanol, potassium salt,tert-butoxypotassium,potassium-t-butoxide,t-buok
IUPAC Name	potassium;2-methylpropan-2-olate
Molecular Formula	C₄H₉KO
EINECS Number	212-740-3
Specific Gravity	0.929

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