missing translation for 'onlineSavingsMsg'
Learn More
  1. Home
  2. Products
  3. Chemicals
  4. Organometallic Compounds
  5. Organolead
  6. 11482987

Lead(IV) acetate, 96% (dry wt.), stab. with 5-10% glacial acetic acid

Product Code. 11482987
Change view
Click to view available options
Quantity:
50 g
Unit Size:
50g
1 product options available for selection
Product selection table with 1 available options. Use arrow keys to navigate and Enter or Space to select.
Product Code. Quantity Unit Size
11482987 50 g 50g
Use arrow keys to navigate between rows. Press Enter or Space to select a product option. 1 options available.
1 options
This item is not returnable. View return policy
Product Code. 11482987 Supplier Thermo Scientific Alfa Aesar Supplier No. A15551.18
 Restricted Item
In Stock
Add to basket

missing translation for 'validMainframeMsg'

This item is not returnable. View return policy

Description

CAS: 546-67-8 | C8H12O8Pb | 443.40 g/mol

Lead(IV) acetate is an important oxidizing agent and a source of acetyloxy group used in organic synthesis. For example, 1,4-dioxene is prepared from dioxane involving 2-acetoxy-1,4-dioxane as an intermediate. Similarly, it is used for the preparation of bis(trifluoromethyl)diazomethane from hexafluoroacetone hydrazone. It also reacts with alkenes, alcohols having a delta-proton and di-n-butyl d-tartrate to get gamma-lactones, cyclic ethers and n-butyl glyoxylate respectively. It induces the cleavage of 1,2-diols to the corresponding aldehydes or ketones. It is actively involved in the Kochi reaction for the decarboxylation of carboxylic acids to alkyl halides and used as an alternative reagent to bromine in the Hofmann rearrangement.

This Thermo Scientific brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific.

Applications
Lead(IV) acetate is an important oxidizing agent and a source of acetyloxy group used in organic synthesis. For example, 1,4-dioxene is prepared from dioxane involving 2-acetoxy-1,4-dioxane as an intermediate. Similarly, it is used for the preparation of bis(trifluoromethyl)diazomethane from hexafluoroacetone hydrazone. It also reacts with alkenes, alcohols having a delta-proton and di-n-butyl d-tartrate to get gamma-lactones, cyclic ethers and n-butyl glyoxylate respectively. It induces the cleavage of 1,2-diols to the corresponding aldehydes or ketones. It is actively involved in the Kochi reaction for the decarboxylation of carboxylic acids to alkyl halides and used as an alternative reagent to bromine in the Hofmann rearrangement.

Solubility
Soluble in water, ethanol, chloroform, benzene, nitrobenzene, tetrachloroethane, nitric acid, hot acetic acid and hydrochloric acid.

Notes
Air and moisture sensitive. Store in cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with alcohols, strong acids and strong reducing agents.
TRUSTED_SUSTAINABILITY

Specifications

CAS 546-67-8
Melting Point 175°C
Density 2.28
Molecular Formula C8H12O8Pb
Linear Formula Pb(OOCCH3)4
MDL Number MFCD00008693
Quantity 50 g
UN Number UN1616
Beilstein 3595640
Sensitivity Moisture sensitive
Merck Index 14,5423
Synonym lead iv acetate
Solubility Information Soluble aq. soln.,ethanol,chloroform,benzene,nitrobenzene,tetrachloroethane,nitric acid,hot acetic acid and hydrochloric acid.
InChI Key ACKFDYCQCBEDNU-UHFFFAOYSA-J
SMILES [Pb++].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O
IUPAC Name λ²-lead(2+) tetraacetate
Molecular Weight (g/mol) 443.40
PubChem CID 50931538
Formula Weight 443.37
Percent Purity 96%
Assay (dry wt.)
Chemical Name or Material Lead(IV) acetate, stabilized with 5 to 10% glacial acetic acid
Show More Show Less

Safety and Handling

compliance-icons compliance-icons compliance-icons
Product Identifier
  • Lead(IV) acetate, stabilized with 5-10% glacial acetic acid
 Signal Word
  • Danger
 Hazard Category
  • Acute toxicity Category 4
  • LONG-TERM AQUATIC HAZARD Chronic 1
  • ACUTE AQUATIC Acute 1
  • Reproductive toxicity Category 1A
  • Specific target organ toxicity after repeated exposure Category 2
 Hazard Statement
  • H302-Harmful if swallowed.
  • H332-Harmful if inhaled.
  • H360Df-May damage the unborn child. Suspected of damaging fertility.
  • H373-May cause damage to organs.
  • H400-Very toxic to aquatic life.
  • H410-Very toxic to aquatic life with long lasting effects.
 Precautionary Statement
  • P264-Wash face, hands and anyexposed skin thoroughly after handling.
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
  • P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P312-Call a POISON CENTER/doctor/if you feel unwell.
 Supplemental information
  • MIXTURE LIST-Contain: Acetic acid, lead(4+) salt
SDS

RUO – Research Use Only

Product Title
Select an issue

By clicking Submit, you acknowledge that you may be contacted by Fisher Scientific in regards to the feedback you have provided in this form. We will not share your information for any other purposes. All contact information provided shall also be maintained in accordance with our Privacy Policy.