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  6. Gadolinium(III) isopropoxide, 99.9% (metals basis), 5% w/v in toluene/isopropanol (3:2)

Gadolinium(III) isopropoxide, 99.9% (metals basis), 5% w/v in toluene/isopropanol (3:2)

Product Code. 11329967
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Product Code. 11329967 Supplier Thermo Scientific Alfa Aesar Supplier No. 042277.AC
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Description

Precursor for Gd2O3 films using Sol-Gel process | CAS: 14532-05-9 | C9H21GdO3 | 334.51 g/mol

It is employed in the catalyst action which is used in a ring opening of meso-aziridines with trimethylsilyl azide. In many asymmetric catalysis applications, glove box and Schlenk techniques should be employed to prevent exposure of the rare earth catalyst to air and moisture, which can be detrimental to the reaction outcome.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

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Chemical Identifiers

CAS 14532-05-9
Molecular Formula C9H21GdO3
Molecular Weight (g/mol) 334.51
MDL Number MFCD00144381
InChI Key VJLSFXQJAXVOEQ-UHFFFAOYSA-N
Synonym gadolinium iii isopropoxide, triisopropoxygadolinium, gadolinium isopropoxide, acmc-20akue, gadolinium triisopropoxide, gadolinium tripropan-2-olate, gadolinium-i-propoxide, gadolinium 3+ ion tris propan-2-olate, gadolinium 3+ tris propan-2-olate
PubChem CID 15047187
IUPAC Name gadolinium(3+);propan-2-olate
SMILES [Gd+3].CC(C)[O-].CC(C)[O-].CC(C)[O-]

Specifications

Color Yellow
Odor Aromatic
Linear Formula Gd[OCH(CH3)2]3
Quantity 25 mL
UN Number UN1993
Sensitivity Moisture sensitive
Solubility Information Hydrolyzes slowly in water.
Formula Weight 334.51
Percent Purity 99.9%
Concentration or Composition (by Analyte or Components) 5% w/v in toluene/isopropanol (3:2)
Physical Form Liquid
Assay (metals basis)
Chemical Name or Material Gadolinium(III) isopropoxide
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