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Organoaluminum

Organoaluminum compounds possess direct bonds between carbon and aluminum atoms. Predominantly electrophilic, these compounds typically act as Lewis acids in reactions and play a large role in the field of organometallic chemistry.

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1

Diisobutylaluminium hydride, 1M solution in hexane, AcroSeal™

CAS: 1191-15-7 | C8H19Al | 142.22 g/mol

Linear Formula [(CH3)2CHCH2]2AlH
Molecular Weight (g/mol) 142.22
Physical Form Solution
Chemical Name or Material Diisobutylaluminium hydride
Merck Index 15, 3212
Density 0.7010g/mL
Name Note 1M Solution in Hexane
Fieser 01,260; 02,140; 03,101; 04,158; 05,224; 06,198; 07,111; 08,173; 09,171; 10,149; 11,185; 12,191; 13,115; 14,138; 15,137; 16,27; 17,123
CAS 110-54-3
Health Hazard 3 GHS P Statement
IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses,if present and easy to do.
Continue rinsing.
Keep away from heat/sparks/open flames/hot surfaces.
- No smoking.
Wear protective g
MDL Number MFCD00008928
Health Hazard 2 GHS H Statement
May be fatal if swallowed and enters airways.
Toxic to aquatic life with long lasting effects.
Causes severe skin burns and eye damage.
May cause drowsiness or dizziness.
May cause damage to organs through p
Solubility Information Solubility in water: reacts
Flash Point −23°C
Health Hazard 1 GHS Signal Word: Danger
Synonym DIBAL-H
Beilstein 04, IV, 4400
Molecular Formula C8H19Al
EINECS Number 214-729-9
Formula Weight 142.22
Specific Gravity 0.701
Melting Point -70.0°C
2
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Diisobutylaluminium hydride, 1.2M (20 wt%) solution in toluene, AcroSeal™

CAS: 1191-15-7 | C8H19Al | 142.22 g/mol

Boiling Point 110.0°C
Linear Formula [(CH3)2CHCH2]2AIH
Molecular Weight (g/mol) 142.22
Physical Form Solution
Chemical Name or Material Diisobutylaluminium hydride
Merck Index 15, 3212
Density 0.8480g/mL
Fieser 01,260; 02,140; 03,101; 04,158; 05,224; 06,198; 07,111; 08,173; 09,171; 10,149; 11,185; 12,191; 13,115; 14,138; 15,137; 16,27; 17,123
CAS 108-88-3
Health Hazard 3 GHS P Statement
IF SWALLOWED: rinse mouth.
Do NOT induce vomiting.
Wear eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses,if present and easy to do.
Continue rinsi
MDL Number MFCD00008928
Health Hazard 2 GHS H Statement
Causes severe skin burns and eye damage.
May be fatal if swallowed and enters airways.
May cause damage to organs through prolonged or repeated exposure.
Suspected of damaging the unborn child.
May cause dro
Solubility Information Solubility in water: reacts violently. Other solubilities: miscible with saturated aliphatic and aromatic,hydrocarbons
Flash Point 4°C
Health Hazard 1 GHS Signal Word: Danger
Synonym DIBAL-H
Beilstein 04, IV, 4400
Molecular Formula C8H19Al
EINECS Number 214-729-9
Formula Weight 142.22
Specific Gravity 0.848
3
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Aluminum acetylacetonate, 97%

CAS: 13963-57-0 Molecular Formula: C15H21AlO6 Molecular Weight (g/mol): 324.31 MDL Number: MFCD00000013 InChI Key: KILURZWTCGSYRE-LNTINUHCSA-K Synonym: aluminum 2, 4-pentanedionate IUPAC Name: aluminium(3+) tris((2Z)-4-oxopent-2-en-2-olate) SMILES: [Al+3].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O

CAS 13963-57-0
Molecular Weight (g/mol) 324.31
MDL Number MFCD00000013
SMILES [Al+3].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O
Synonym aluminum 2, 4-pentanedionate
IUPAC Name aluminium(3+) tris((2Z)-4-oxopent-2-en-2-olate)
InChI Key KILURZWTCGSYRE-LNTINUHCSA-K
Molecular Formula C15H21AlO6
4

Aluminum 2,4-pentanedionate

CAS: 13963-57-0 Molecular Formula: C15H21AlO6 Molecular Weight (g/mol): 324.31 MDL Number: MFCD00000013 InChI Key: KILURZWTCGSYRE-LNTINUHCSA-K Synonym: Aluminum acetylacetonate; Tris(acetylacetonato)aluminum(III) IUPAC Name: aluminium(3+) tris((2Z)-4-oxopent-2-en-2-olate) SMILES: [Al+3].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O

CAS 13963-57-0
Molecular Weight (g/mol) 324.31
MDL Number MFCD00000013
SMILES [Al+3].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O
Synonym Aluminum acetylacetonate; Tris(acetylacetonato)aluminum(III)
IUPAC Name aluminium(3+) tris((2Z)-4-oxopent-2-en-2-olate)
InChI Key KILURZWTCGSYRE-LNTINUHCSA-K
Molecular Formula C15H21AlO6
6

Sodium bis(2-methoxyethoxy)aluminum hydride, 70% w/w in toluene.

CAS: 22722-98-1 Molecular Formula: C6H16AlNaO4 MDL Number: MFCD00011631 Synonym: Sodium dihydrobis(2-methoxyethoxy)aluminate

CAS 22722-98-1
MDL Number MFCD00011631
Synonym Sodium dihydrobis(2-methoxyethoxy)aluminate
Molecular Formula C6H16AlNaO4
7

Aluminum acrylate

CAS: 15743-20-1 Molecular Formula: C9H12AlO6 Molecular Weight (g/mol): 243.171 MDL Number: MFCD00078421 InChI Key: UNGWYUCJMHZVEX-UHFFFAOYSA-N Synonym: aluminum acrylate PubChem CID: 131874419 IUPAC Name: aluminum;prop-2-enoic acid SMILES: C=CC(=O)O.C=CC(=O)O.C=CC(=O)O.[Al]

PubChem CID 131874419
CAS 15743-20-1
Molecular Weight (g/mol) 243.171
MDL Number MFCD00078421
SMILES C=CC(=O)O.C=CC(=O)O.C=CC(=O)O.[Al]
Synonym aluminum acrylate
IUPAC Name aluminum;prop-2-enoic acid
InChI Key UNGWYUCJMHZVEX-UHFFFAOYSA-N
Molecular Formula C9H12AlO6
8

mu-Chloro-mu-methylenebis(cyclopentadienyl)titaniumdimethylaluminum, 0.5M in toluene

CAS: 67719-69-1 Molecular Formula: C13H18AlClTi MDL Number: MFCD00151575 Synonym: Tebbe Reagent

CAS 67719-69-1
MDL Number MFCD00151575
Synonym Tebbe Reagent
Molecular Formula C13H18AlClTi
9

Aluminum 2,4-pentanedionate, 99.995+% (metals basis)

CAS: 13963-57-0 Molecular Formula: C15H21AlO6 Molecular Weight (g/mol): 324.31 MDL Number: MFCD00000013 InChI Key: KILURZWTCGSYRE-LNTINUHCSA-K Synonym: Aluminum acetylacetonate IUPAC Name: aluminium(3+) tris((2Z)-4-oxopent-2-en-2-olate) SMILES: [Al+3].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O

CAS 13963-57-0
Molecular Weight (g/mol) 324.31
MDL Number MFCD00000013
SMILES [Al+3].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O
Synonym Aluminum acetylacetonate
IUPAC Name aluminium(3+) tris((2Z)-4-oxopent-2-en-2-olate)
InChI Key KILURZWTCGSYRE-LNTINUHCSA-K
Molecular Formula C15H21AlO6
10

Aluminum di(isopropoxide)acetoacetic ester chelate, Al 9.6% min

CAS: 14782-75-3 Molecular Formula: C12H23AlO5 MDL Number: MFCD00135521

CAS 14782-75-3
MDL Number MFCD00135521
Molecular Formula C12H23AlO5
11

Aluminum magnesium isopropoxide, 99.9% (metals basis), 10% w/v in isopropanol

CAS: 69207-83-6 MDL Number: MFCD00070426 Synonym: Magnesium aluminum isopropoxide

CAS 69207-83-6
MDL Number MFCD00070426
Synonym Magnesium aluminum isopropoxide
12

Aluminum magnesium isopropoxide, 99.95+% (metals basis)

CAS: 69207-83-6 MDL Number: MFCD00070426

CAS 69207-83-6
MDL Number MFCD00070426
13

Diisobutylaluminum hydride, 1M solution in hexane, Thermo Scientific™

CAS: 1191-15-7 MDL Number: MFCD00008928

CAS 1191-15-7
MDL Number MFCD00008928
14

Aluminum nickel isopropoxide, 99.9% (metals basis), Thermo Scientific™

CAS: 70504-57-3 MDL Number: MFCD00143593

CAS 70504-57-3
MDL Number MFCD00143593
15

Diisobutylaluminum hydride, 25% w/w in hexane, Thermo Scientific™

CAS: 1191-15-7 MDL Number: MFCD00008928 Synonym: DIBAL-H

CAS 1191-15-7
MDL Number MFCD00008928
Synonym DIBAL-H